Sintesis Bio-Oil dari Bonggol Jagung menggunakan Proses Pirolisis
DOI:
https://doi.org/10.28926/briliant.v10i2.2023Keywords:
Bio-Oil, Corn Cob, PyrolysisAbstract
Bio-Oil is a raw material that can be produced through various methods, one of which is the biomass pyrolysis process. Biomass pyrolysis has been extensively studied and has shown promising potential as an alternative fuel due to its lignocellulose content. In Indonesia, corn production reaches 23.1 million tons, resulting in waste in the form of corn cobs. This study employed the fast pyrolysis method to convert corn cobs into Bio-Oil. The pyrolysis process was conducted in a sealed reactor, externally heated to a temperature of 400°C. The corn cobs used as raw material were first crushed and sieved to achieve a uniform particle size of 20 mesh. Subsequently, the corn cobs were placed into the pyrolysis reactor, with residence times varied at 40, 60, 80, 100, and 120 minutes. Upon completion of the pyrolysis process, the resulting products, consisting of Bio-Oil, charcoal, and pyrolysis gas, were separated and analyzed for Bio-Oil yield, density, viscosity, and calorific value. Chemical composition analysis was performed using Gas Chromatography-Mass Spectrometry (GC-MS) to identify the main compounds present in the Bio-Oil. The highest yield was obtained with a particle size of 20 mesh and a residence time of 120 minutes, resulting in a yield of 72.4632%, a density of 1.3018 kg/m³, a viscosity of 1.6712 mm²/s, and a calorific value of 6.640 Kcal/kg. GC-MS analysis revealed an acetic acid content of 37.49% and a methyl ester content of 22.19%.
References
Amelyanti, E., Usman, T., & Rahmalia, W. (2023). Determination of Optimum Conditions for Synthesis of Methyl Ester from Bleached Crude Palm Oil Using Sn-Zeolite and Red Mud Catalysts. Jurnal Presipitasi : Media Komunikasi Dan Pengembangan Teknik Lingkungan, 20(2), 267–279. https://doi.org/10.14710/presipitasi.v20i2.267-279
Dewayanto, N., & Nordin, M. R. (2016). Catalytic Pyrolysis of Biomass to Synthesize Bio-Oil and Chemicals: A Review. CHEMICA: Jurnal Teknik Kimia, 2(1), 29. https://doi.org/10.26555/chemica.v2i1.4566
Hapsari, N. A. P., & Wibowo, A. A. (2023). Studi Kasus Simulasi Reaktor Equilibrium Pada Produksi Metil Asetat Menggunakan Software Chemcad. DISTILAT: Jurnal Teknologi Separasi, 6(2), 49–55. https://doi.org/10.33795/distilat.v6i2.74
Ibadurrohman, I. A., Hamidi, N., & Yuliati, L. (2021). Pengaruh Panjang Rantai Karbon dan Derajat Ketidakjenuhan terhadap Karakteristik Pembakaran Droplet Asam Lemak Tunggal. Jurnal Rekayasa Mesin, 12(2), 331–347. https://doi.org/10.21776/ub.jrm.2021.012.02.11
Iriani, P., & Ambriani, P. (2020). Analisis Hasil Asetogenesis Bungkil Kopi Pada Sistem Biodigester Anaerob Dua Tahap. Jurnal Teknik Energi, 4(2), 317–321. https://doi.org/10.35313/energi.v4i2.1746
Jenita, J., Abrina Anggraini, S. P., Yuniningsih, S., & Kimia, T. (2019). Pembuatan Asap Cair dari Tempurung Kelapa, Tongkol Jagung, dan Bambu Menggunakan Proses Slow Pyrolysis. Jurnal Penelitian Teknik Sipil dan Teknik Kimia, 3(1), 42-49. https://publikasi.unitri.ac.id/index.php/teknik
Kanaujia, P. K., Sharma, Y. K., Garg, M. O., Tripathi, D., & Singh, R. (2014). Review Of Analytical Strategies In The Production And Upgrading Of Bio-Oils Derived From Lignocellulosic Biomass. Journal of Analytical and Applied Pyrolysis, 105, 55–74. https://doi.org/10.1016/j.jaap.2013.10.004
Kiswanto, C. M. J., & Rubianto, L. (2023). Pengaruh Waktu Fermentasi Dan Konsentrasi H2SO4 Terhadap Kadar Glukosa Pada Pembuatan Bioetanol Dari Tongkol Jagung. DISTILAT: Jurnal Teknologi Separasi, 8(4), 765–770. https://doi.org/10.33795/distilat.v8i4.452
Kumar, R., Strezov, V., Lovell, E., Kan, T., Weldekidan, H., He, J., Dastjerdi, B., & Scott, J. (2019). Bio-Oil Upgrading With Catalytic Pyrolysis Of Biomass Using Copper/Zeolite-Nickel/Zeolite And Copper-Nickel/Zeolite Catalysts. Bioresource Technology, 279, 404–409. https://doi.org/10.1016/j.biortech.2019.01.067
Ladoni, R., Sjah, T., & Ibrahim, I. (2023). Analisis Perkembangan Produksi Jagung Di Kabupaten Lombok Timur. AGROTEKSOS, 33(1), 157. https://doi.org/10.29303/agroteksos.v33i1.816
Lomban, S. D., Sahara, & Azijah, Z. (2022). Dampak Covid-19 Terhadap Kinerja Ekspor Dan Impor Sektor Pertanian Indonesia: Pendekatan Analisis Input Output. Buletin Ilmiah Litbang Perdagangan, 16(2), 167-184. https://doi.org/10.55981/bilp.2022.11
Muzdalifah, M., Syarif, T., & Aladin, A. (2020). Potensi Pemanfatan Limbah Biomassa Serbuk Gergaji Kayu Besi (Eusideroxylon Zwageri) Menjadi Asap Cair Melalui Proses Pirolisis. ILTEK : Jurnal Teknologi, 15(2), 78–81. https://doi.org/10.47398/iltek.v15i2.523
Perry. (2008). Perry’s Chemical Engineers’ handbook, 8th edition, McGrowHill Companies, Inc., United State. DOI: 10.1036/0071422943
Pupu, A., Yuliana Sari, D., Ade Maya, M., Ragil, M., Agil Soeharja, M., & Teknologi Adhi Tama Surabaya, I. (2024). Review Kandungan Metil Ester Dalam Biodiesel Generasi Ke-3 Mikroalga Dan Penggunaan Katalis. Prosiding Seminar Nasional Teknologi Industri Berkelanjutan IV (SENASTITAN IV) Surabaya.
Rahman, M., Liu, R., & Cai, J. (2018). Catalytic Fast Pyrolysis Of Biomass Over Zeolites For High Quality Bio-Oil – A Review. Fuel Processing Technology, 180, 32–46. https://doi.org/10.1016/j.fuproc.2018.08.002
Rahmatullah, Putri. R. W., & Nurisman. E. (2019). Produksi Bio-Oil Dari Limbah Kulit Durian Dengan Proses Pirolisis Lambat. Jurnal Teknik Kimia, 25(2), 50–53. https://doi.org/10.36706/jtk.v25i2.425
Saputra, D., Erlina, Y., & Barbara, B. (2022). Analisis Trend Produksi Dan Konsumsi Jagung Pipilan Di Indonesia. JOURNAL SOCIO ECONOMICS AGRICULTURAL, 17(1), 30–46. https://doi.org/10.52850/jsea.v17i1.4340
Selpiana, S., Susmanto, P., Cundari, L., Putri, R. W., Ibrahim, O., & Oktari, D. (2019). Konversi Limbah Plastik Jenis Expanded Polystyrene Menjadi Bahan Bakar Cair Dengan Proses Perengkahan Katalitik. Jurnal Dinamika Penelitian Industri, 30(2). 123-128 https://doi.org/10.28959/jdpi.v30i2.5592
Sitorus, I. P. B., Meriatna, M., Masrullita, M., Jalaluddin, J., & Nurlaila, R. (2023). Karakterisasi Metil Ester Dari Minyak Kepayang (Pangium Edule Reinw) Melalui Proses Transesterifikasi Menggunakan Katalis Kulit Jengkol (Archidendron Pauciflorum). Chemical Engineering Journal Storage (CEJS), 3(6), 829. https://doi.org/10.29103/cejs.v3i6.11968
Syachbudy, Q. Q. (2023). Tata Kelola Rantai Nilai Komoditas Jagung Di Provinsi Gorontalo. Mimbar Agribisnis : Jurnal Pemikiran Masyarakat Ilmiah Berwawasan Agribisnis, 9(1), 291. https://doi.org/10.25157/ma.v9i1.8384
Wibowo, S. (2016). Karakteristik Bio-Oil Dari Limbah Industri Hasil Hutan Menggunakan Pirolisis Cepat. Jurnal Penelitian Hasil Hutan, 34(1), 61–67. https://doi.org/10.20886/jphh.2016.34.1.61-76
Wicakso, D. R., Lestari, R. A., Maulana, R., Andriya, D., Yani, J. A., 36 Banjarbaru, K. M., & Selatan, K. (2021). Pengaruh Suhu Pada Proses Catalytic Cracking Untuk Up Grading Bio-Oil Dari Hasil Pirolisis Tandan Kosong Sawit (TKS) Dengan Katalisator Lempung Gambut. Prosiding Seminar Nasional Lingkungan Lahan Basah (Vol. 6).
Downloads
Published
Issue
Section
License
Copyright (c) 2025 Briliant: Jurnal Riset dan Konseptual

This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.